In our previous blog post we asked if the Schrödinger equation is Galilean covariant. That is, if the equation has a solution in a frame, can we – in a beautiful way – transform the solution and obtain the solution in a moving frame?
Newtonian mechanics is Galilean covariant. If we have a history of mechanical system, we can – in a simple way – transform the solution to a frame moving at a constant velocity v. The transformed solution satisfies newtonian mechanics in the moving frame.
Huygens's principle
Let us have a wave. Using Huygens's principle, we can easily construct an approximation for the diffraction pattern created by a pinhole in a screen.
|
| | | | ) ) )
| pinhole
|
wave --> v screen diffracted wave
^ y
|
------> x moving frame
--> v
Let the velocity of the wave be v. Let us switch to a moving frame which comoves with the incoming wave.
In the comoving frame, the incoming wave is static. Can we use Huygens's principle for a static wave?
The screen is moving against a static wave. How can the screen create the diffraction pattern?
If we are looking at water waves, then the frame where water does not flow horizontally, can be defined as a preferred frame.
Does it make sense to demand that Huygens's principle should work in any other frame than the preferred frame?
For water waves, a disturbance at a location r will spread to every direction at some fixed speed v relative to the water. It makes little sense to use any other frame than the frame in which water is static.
In the case of the Schrödinger equation, there is no self-evident preferred frame. In principle, we should be able to use any inertial frame.
Richard Feynman derived the Schrödinger equation from a path integral, i.e., Huygens's principle
David Derbes (1996) describes how Richard Feynman used a path integral approach to derive the Schrödinger equation. The path integral has much the same idea as in Huygens's principle. If we know the wave function
ψ(t, r)
at a time t₀, we can construct the wave at a later time t₁ by summing the contributions of ψ(t₀, r) for each point r in space.
Huygens said that each point r acts as a new "source" of a new mini-wave. At a later time, the wave's crests are where there is a constructive interference of the mini-waves.
Huygens's principle works right for light
|
| | | ---> c ) ) )
| pinhole
^
|
-------> ---> v
moving frame
Let us assume that the incoming wave is electromagnetic. Let us switch to a moving frame. We assume that v << c, so that we can ignore time dilation.
In the moving frame, there is a redshift of the incoming wave. Its frequency is lower. But the redshift is canceled by the blueshift for the screen and the pinhole moving to the left.
The pinhole "sees" the frequency of the wave identical in the laboratory frame and the moving frame.
Let us then switch back to the laboratory frame. The pinhole works as a source of waves (a transmitter).
The Merzbacher textbook contains a proof of Galilean covariance for Schrödinger
The textbook by Eugen Merzbacher, Quantum mechanics (1961, printed in 1998) contains a proof of Galilean invariance for the Schrödinger equation, on pages 75 - 78.
The key observation is that one can transform a plane wave
ψ(t, r) = exp(i (p • r - E t) / ħ)
to a frame moving at a velocity v by the formula
ψv(t, r) = exp(i (m v • r - m v² t / 2))
* ψ(t, r - v t).
That is one can use the simple transformation ψ(t, r - v t) if one multiplies it with a factor which does not depend on p.
An arbitrary sum Ψ of plane waves can be transformed by multiplying all of them by the same factor. Relations like Ψ = Φ are preserved in the transformation. Everything behaves very well.
If ψ satisfies the Schrödinger equation
in the laboratory frame, then Merzbacher shows that ψv satisfies the corresponding equation in a moving frame whose velocity is v. The potential V is mapped in the trivial way to the moving frame.
The Green function or path integral approach
Let us have a plane wave where the momentum p is very precisely 0.
particle
• v <--- | mirror
p = 0
The wave function ψ of the particle is essentially a constant complex number,
ψ = C.
What happens when a steep potential wall (mirror) plows into the constant wave function?
We had problems figuring out how Huygens's principle behaves in this case. The wave function is constant. There is no propagating wave. How could we apply Huygens's principle if there is no wave.
Green's functions give us a clue. Let us have a point r. We imagine a sharp impulse "hitting" the Schrödinger equation at the point r. The impulse response (Green's function) contains waves of all wavelengths.
Previously, we have used the allegory that a "sharp hammer" hits a table.
The hammers hits simultaneously all points to the left of the mirror. Short wavelegths are canceled by destructive interference. Very long wavelengths remain.
How is a very long wavelength reflected from the mirror?
Newtonian physics says that the reflected particle should have a velocity 2 v to the left. This gives us the momentum p of the wave.
The phase velocity of the reflected wave is v to the left. The wave has a constant value on the surface of the mirror. This constant value must match C. This determines the phase of the reflected wave.
We were able to determine the momentum and the phase of the reflected wave.
Even though the constant value C of ψ does not have a "phase", it does determine the phase of the reflected wave. This resolves the conceptual problem we had with Huygens's principle.
Diffraction and Huygens's principle
|
| | | | ) ) )
| pinhole
|
We had problems understanding how Huygens's principle can handle diffraction if a screen with a pinhole plows into a wave function ψ where p = 0.
In the comoving frame of the screen, the pinhole creates half-spherical waves propagating from the pinhole.
But in the laboratory frame, p = 0, and the screen plows into a constant wave function. How can it then create waves moving into many directions? The "input" to the pinhole is constant and does not contain any oscillation.
In the case of the mirror, the momentum of the reflected particle and the continuity of the wave function determined the wavelength and the phase of the generated wave.
The solution to the mystery probably is the same for the pinhole: the momentum of the diffracted particle gives p and continuity gives the phase.
Conclusions
The Schrödinger equation is Galilean covariant.
We can use Green's functions (path integral) to build solutions for the equation.